お問い合わせ information

Product Explanation ▶　[Li@C₆₀](PF₆)
Standard product is microcrystalline powder composed of Li+@C₆₀ and PF6  in 1:1 ratio.
The Purity of [Li@C₆₀] (PF6) is > 95% (measured value).
It is found that  “rock-salt crystal” may be formed by using an appropriate re-crystallization process.

Product Speciflcation ▶
◇Li：0.70～0.80%， C：80.0～83.0 % by Elemental Analysis
◇TOF-MS Spectrum Chart (positive mode/ negative mode) accompanies the product as reference data.
◇Store (refrigerate) in a cool, dark place.

Resesarch Application Examples ▶
1)S. Aoyagi et al, Rock-Salt-Type Crystal of Thermally Contracted C60 with Encapsulated   Lithium Cation, Angev. Chem. Int. Ed.,2012,51,1-6
(Electrostatic interaction, Dielectric properties, Molecular switches, Ultra-high-density recording)

2)S.Fukuzumi et al, Ion-Controlled On-Off Switch of Electron Transfer from Tetrathiafulvalene Calix[4]pyrroles to Li+@C₆₀, J.Am.Chem.Soc.,2011,133,15938-15941
(New charge accumulation device, new organic batteries)

3)K.Ohkubo et al.,Strong supramolecular binding of Li+@C₆₀ with sulfonated meso-tetraphenylporphyrins and long-lived photoinduced charge separation,Chem. Commun. 06 March 2012, DOI:10.1039/c2cc31186k
(Organic Electronic Devices, Photoelectric Conversion Devices, Photo Voltaic Cell)

4)H.Okada et al,The Li+@C₆₀ functionalization -Synthesis of Li@C60PCBM cations, The 42nd F-N-G General Sympo. 2012,3,6-8, Tokyo
(Organic Electronic Devices, Photoelectric Conversion Devices, Photo Voltaic Cell)
C60PCBM cations, The 42nd F-N-G General Sympo. 2012,3,6-8, Tokyo
(Organic Electronic Devices, Photoelectric Conversion Devices, Photo Voltaic Cell)

+ ￥2,000 Domestic shipping